Abstract




 
   

IJE TRANSACTIONS C: Aspects Vol. 27, No. 6 (June 2014) 939-944   

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  ELECTRODEPOSITION OF NANO HYDROXYAPATITE COATING ON BIODEGRADABLE MG-ZN SCAFFOLD (TECHNICAL NOTE)
 
Z. S. Seyedraoufi, S. Mirdamadi and S. Rastegari
 
( Received: September 11, 2013 – Accepted: December 12, 2013 )
 
 

Abstract    Magnesium has been recently recognized as a biodegradation metal for bone substitute application. In the present work, porous magnesium-zinc scaffolds were prepared by powder metallurgical process and nano hydroxyapatite (HAP) coating on the Mg-3Zn (wt.%) scaffold was prepared by pulse electrodeposition and alkali treatment processes to improve the corrosion resistance of scaffold. The results indicated the as-deposited coating consists of HAP, DCPD and OCP with needle-like and plate-like structures and the post-treated coating was composed of needle-like particles of nano HAP that developed almost perpendicularly to the substrate. Electrochemical tests showed that the corrosion potential of scaffold significantly increased from –1.475 to –1.365 V and the corrosion current density reduced 1.5-fold in comparison to the scaffold modified by nano hydroxyapatite coating.

 

Keywords    Biodegradable Mg–Zn scaffold, Hydroxyapatite coating, electrodeposition, alkali treatment, Corrosion resistance

 

چکیده    منیزیم اخیرا به عنوان یک فلز زیست تخریب پذیر جهت کاربرد جایگزین استخوان شناخته شده است. در کار حاضر، داربست های منیزیم-روی متخلخل از طریق فرآیند متالورژی پودر آماده شدند و پوشش نانوهیدروکسی آپاتیت بر روی داربست منیزیمی حاوی 3 درصد وزنی عنصر روی توسط فرآیندهای رسوب الکتریکی پالسی و عملیات قلیایی جهت بهبود مقاومت خوردگی داربست ایجاد شد. نتایج نشان داد پوشش حاصل از فرآیند رسوب الکتریکی پالسی شامل HAP با ساختار شبه سوزنی و مقداری نیز شامل ترکیبات DCPD وOCP با ساختار شبه پلیتی می باشد. پوشش حاصل از عملیات قلیایی نیز از ذرات شبه سوزنی نانو HAP تقریبا عمود بر زیرپایه تشکیل شده بود. تست های الکتروشیمیایی نشان داد که پتانسیل خوردگی داربست به طور قابل توجه از 1.475- به 1.365- ولت افزایش و دانسیته چریان خوردگی در حدود یک و نیم برابر در مقایسه با داربست اصلاح شده توسط پوشش نانو هیدروکسی آپاتیت کاهش یافت.

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