IJE TRANSACTIONS B: Applications Vol. 32, No. 5 (May 2019) 641-646   

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P. V. Melnikov, A. E. Kozhukhova, A. O. Naumova, N. A. Yashtulov and N. K. Zaitsev
( Received: January 20, 2019 – Accepted in Revised Form: May 02, 2019 )

Abstract    A special sensitive element based on the novel composite material was created. The sensor has a linear calibration and is resistant to aliphatic hydrocarbons, in particular aviation fuel. A low cost and easy-to-implement method for calibrating the sensor was proposed. Temperature dependence of the oxygen mass transfer coefficient kL was measured for aviation fuel TS-1 (Russian equivalent of Jet A-1) in the temperature range of 10 to 40 °C as a demonstration of the sensor capabilities. The dependence found obeys the Arrhenius equation with the parameters EA = 21.7 ± 1.5 kJ/mol, kL0 = 1080 ± 90 m·h-1. The resistance to mechanical action is one of the important advantages over the sensor made of a sol-gel matrix with a protective coating. Damage to some part of the surface does not change the properties of the entire sensor, since the composite material contains a large number of isolated particles with a dye.


Keywords    Oxygen Sensor; Optical Sensor; Phosphorescence Quenching; Organic Solvents; Oxygen Transfer Rate; Aviation Fuel; Resistance to Aliphatic Hydrocarbons



یک عنصر حساس ویژه بر اساس مواد کامپوزیتی جدید ابداع گردید. سنسور مورد نظر یک کالیبراسیون خطی دارد و به هیدروکربن های آلیفاتیک، مخصوصا سوخت هواپیما، مقاوم است. یک روش کم هزینه و آسان برای پیاده سازی کالیبراسیون سنسور پیشنهاد شده است. وابستگی دما به ضریب انتقال جرم اکسیژن kL برای سوخت هواپیما TS-1 معادل روسی (Jet A-1) در محدوده دما 10 تا 40 درجه سانتیگراد ظاهرا قابلیت های اندازه گیری سنسور را دارد. وابستگی مشخص شده مطابق معادله آرنینوس با پارامترهای EA = 21.7 ± 1.5 kJ/mol، kL0 = 1080 ± 90 m·h-1 است. مقاومت در برابر فعالیت مکانیکی یکی از مزایای مهم در برابر حسگر ساخته شده از ماتریس sol-gel با پوشش محافظتی است. آسیب به برخی از قسمت های سطح خواص کل سنسور را تغییر نمی دهد، زیرا مواد کامپوزیت شامل تعداد زیادی ذرات جدا شده با رنگ را دارند.


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